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dc.contributor.advisorZebolsky, Donald M.en_US
dc.contributor.authorShearer, Greg Otisen_US
dc.date.accessioned2019-01-10T16:46:05Z
dc.date.available2019-01-10T16:46:05Z
dc.date.issued1971en_US
dc.identifier.urihttp://hdl.handle.net/10504/120930
dc.description.abstractSeveral articles (1,2,3A ) have appeared in which metal-thiourea complex formation constants have been calculated from the half-wave shifts of the complexes. However, the Lingane and DeFord-Hume Equations which were used can only be applied to the complexes of reversible metal ions. | The purpose of this work was to explore an extension of the DeFord-Hume Equation to calculate the complex formation constants of an irreversible metal ion, in this case Ni (IT). In order to use the method previously used by Crow and Westwood (5), a reversible metal-thiourea system had to be studied thoroughly. To make full use of the data, a computer least squares program was used to solve a set of simultaneous equations, as Klatt and Rouseff proposed (6 ). The nickel(II)-thiourea complex formation constants should then be calculable from the effect of Ni(II) on the Pb(II) wave.en_US
dc.language.isoen_USen_US
dc.publisherCreighton Universityen_US
dc.rightsA non-exclusive distribution right is granted to Creighton University and to ProQuest following the publishing model selected above.en_US
dc.titlePolarographic Study of Metal Thiourea Complexes: a Computer Least Squares Approachen_US
dc.typeThesis
dc.publisher.locationOmaha, Nebraskaen_US
dc.description.noteProQuest Traditional Publishing Optionen_US
dc.contributor.cuauthorShearer, Greg Otisen_US
dc.degree.levelMS (Master of Science)en_US
dc.degree.disciplineChemistry (graduate program)en_US
dc.degree.nameM.S. in Chemistryen_US
dc.degree.grantorGraduate Schoolen_US


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